Reprint of “Seasonal and daily variation of mercury evasion at coastal and off shore sites from the Mediterranean Sea”     

Maria E. Andersson  Katarina Gårdfeldt  Ingvar Wängberg  Francesca Sprovieri  Nicola Pirrone  Oliver Lindqvist 《Marine Chemistry》2007

Dissolved gaseous mercury (DGM) was measured continuously using two newly developed techniques and a manual technique. The continuous techniques were based on the equilibrium between the aqueous and gaseous phase (DGM = Hg_extr / H', Hg_extr is the measured mercury concentration in the gas phase, H' is the Henry's Law coefficient at the desired temperature). In order to calculate the annual mercury evasion from the Mediterranean Sea, diurnal and seasonal measurements of DGM, total gaseous mercury in air (TGM), water temperature and wind speed were performed. During August 2003, March–April 2004 and October–November 2004 measurements of these parameters were conducted on board the RV Urania. The continuous measurements of DGM showed a diurnal variation in concentration, at both coastal and off shore sites, with higher concentrations during daytime than nighttime. The concentration difference could be as large as 130 fM between day and night. The degree of saturation was calculated directly from the measurements, S = Hg_extr / TGM and was found to vary between the different seasons. The highest average degree of saturation (850%) and the largest variation in saturation (600–1150%) was observed during the summer. The spring showed the lowest variation (260–360%) and the lowest average degree of saturation (320%). The autumn also showed a large variation in saturation (500–1070%) but a lower average (740%) compared to the summer cruise. This might be explained by the temperature difference between the different seasons, since that parameter varied the most. The flux from the sea surface was calculated using the gas exchange model developed by Nightingale et al. [Nightingale, P.D., Malin, G., Law, C.S., Watson, A.J., Liss, P.S., Liddicoat, M.I., Boutin, J., Upstill-Goddard, R. C., 2000. In situ evaluation of air–sea gas exchange parameterization using novel conservative and volatile tracers. Global Biogeochemical Cycles, 14(1):373–387]. The evasion varied between the different seasons with the highest evasion during the autumn, 24.6 pmol m^− 2 h^− 1. The summer value was estimated to 22.3 pmol m^− 2 h^− 1 and the spring to 7.6 pmol m^− 2 h^− 1. Using this data the yearly evasion from the Mediterranean Sea surface was estimated to 77 tons.  相似文献   

Bounded relative motion under zonal harmonics perturbations     

Nicola Baresi  Daniel J. Scheeres 《Celestial Mechanics and Dynamical Astronomy》2017,127(4):527-548

The problem of finding natural bounded relative trajectories between the different units of a distributed space system is of great interest to the astrodynamics community. This is because most popular initialization methods still fail to establish long-term bounded relative motion when gravitational perturbations are involved. Recent numerical searches based on dynamical systems theory and ergodic maps have demonstrated that bounded relative trajectories not only exist but may extend up to hundreds of kilometers, i.e., well beyond the reach of currently available techniques. To remedy this, we introduce a novel approach that relies on neither linearized equations nor mean-to-osculating orbit element mappings. The proposed algorithm applies to rotationally symmetric bodies and is based on a numerical method for computing quasi-periodic invariant tori via stroboscopic maps, including extra constraints to fix the average of the nodal period and RAAN drift between two consecutive equatorial plane crossings of the quasi-periodic solutions. In this way, bounded relative trajectories of arbitrary size can be found with great accuracy as long as these are allowed by the natural dynamics and the physical constraints of the system (e.g., the surface of the gravitational attractor). This holds under any number of zonal harmonics perturbations and for arbitrary time intervals as demonstrated by numerical simulations about an Earth-like planet and the highly oblate primary of the binary asteroid (66391) 1999 KW4.  相似文献   

Coastal uplift rate at Matanzas (Cuba) inferred from MIS5e phreatic overgrowths on speleothems          下载免费PDF全文

Jo De Waele  Ilenia M. D'Angeli  Nicola Tisato  Paola Tuccimei  Michele Soligo  Joaquín Ginés  Angel Ginés  Joan J. Fornós  Igor M. Villa  Esteban R. Grau González  Stefano M. Bernasconi  Tomaso R. R. Bontognali 《地学学报》2017,29(2):98-105

Many morphological elements in Cuba's landscape (e.g. marine terraces, tidal notches) demonstrate that coastal uplift has taken place, but the rate at which this occurs is not known. Carbonate phreatic overgrowths on speleothems have been found in a cave in Central North Cuba, ~1 km from the present coastline at 16 m asl. They form exceptional and unique mushroom‐shaped speleothems and balconies decorating the walls of the rooms. These phreatic overgrowths on speleothems (POS) formed at the oscillating air–water interface in sea‐level controlled anchialine lakes. U/Th dating of these overgrowths suggests ages that are compatible with the Marine Isotope Stage 5e (i.e. 130–115 ka). These POS have fixed this sea‐level highstand and demonstrate that this part of Cuba has been subjected to a much lower uplift rate than previously reported, that is, less than 0.1 mm/year since the last interglacial.  相似文献   

East-west trending magnetic anomalies in the Southern Hemisphere of Mars: Modeling analysis and interpretation   总被引：1，自引：0，他引：1  

Lon L. Hood  Nicola C. Richmond  Keith P. Harrison 《Icarus》2007,191(1):113-131

Maps of the vector components of the martian crustal magnetic field over the strongly magnetized Terra Cimmeria/Sirenum region are constructed using Mars Global Surveyor magnetometer data. Although pronounced east-west trending anomalies are present on the radial and north field component maps at the mapping altitude (∼360-380 km), these trends are much less prominent at the lower aerobraking altitude (∼90-150 km). Comparisons with similar maps produced using artificial data at the aerobraking altitude indicate that elongated sources in this region may have maximum lengths along the martian surface of ∼500 km and maximum aspect ratios of ∼2. Iterative forward modeling of several relatively isolated anomalies in the mapped region yields paleomagnetic pole positions consistent with those estimated in previous studies of other anomalies using mapping phase and science phasing orbit data. On this basis, it is inferred that sources in the studied region are most probably magnetized primarily in northward or southward directions. Using this additional constraint, iterative forward modeling is then applied to determine a magnetization distribution that is consistent with data at both the aerobraking altitude and the mapping altitude. The model magnetization distribution, which includes 41 discrete sources, again indicates no highly elongated sources. An examination of surface geology in the region as well as a consideration of the global distribution of anomalies suggests that magmatic intrusions (e.g., subsurface dike swarms), cooling in the presence of water, are the most likely sources of the magnetic anomalies.  相似文献   

Choice chamber experiments to test the attraction of postflexion Rhabdosargus holubi larvae to water of estuarine and riverine origin     

Nicola C. James  Paul D. Cowley  Alan K. Whitfield  Horst Kaiser 《Estuarine, Coastal and Shelf Science》2008

Although the recruitment of larvae and juveniles of marine fishes into estuaries has been well documented, little is known about the factors governing the immigration of estuary-associated marine fishes into estuaries. Fishes have a well-developed sense of smell and it has been suggested by several workers that olfactory cues of freshwater or estuarine origin serve as stimuli, attracting larvae and juveniles of estuary-associated species into estuaries. Attraction of postflexion Rhabdosargus holubi larvae to estuary and river water from the Kowie estuarine system, South Africa, was measured using a rectangular choice chamber. In experiments, conducted during peak recruitment periods, larvae selected estuary and river water with a significantly higher frequency than sea water. This study, the first to assess the possible role of olfaction in the recruitment process of an estuary-associated marine fish species, demonstrates that larvae are able to recognise water from different origins, probably based on odour.  相似文献   

Exploring a landslide inventory created by automated web data mining: the case of Italy     

Franceschini  Rachele  Rosi  Ascanio  Catani  Filippo  Casagli  Nicola 《Landslides》2022,19(4):841-853

Landslides - Nowadays, several systems to set up landslide inventories exist although they rarely rely on automated or real-time updates. Mass media can provide reliable info about natural hazard...  相似文献   

Potential of radiotelescopes for atmospheric line observations: I. Observation principles and transmission curves for selected sites     

Nicola Schneider  Joachim Urban 《Planetary and Space Science》2009,57(12):1419-1433

Existing and planned radiotelescopes working in the millimetre (mm) and sub-millimetre wavelengths range provide the possibility to be used for atmospheric line observations. To scrutinize this potential, we outline the differences and similarities in technical equipment and observing techniques between ground-based aeronomy mm-wave radiometers and radiotelescopes. Comprehensive tables summarizing the technical characteristics of existing and future (sub)-mm radiotelescopes are given. The advantages and disadvantages using radiotelescopes for atmospheric line observations are discussed. In view of the importance of exploring the sub-mm and far-infrared wavelengths range for astronomical observations and atmospheric sciences, we present model calculations of the atmospheric transmission for selected telescope sites (DOME-C/Antarctica, ALMA/Chajnantor, JCMT and CSO on Mauna Kea/Hawaii, KOSMA/Swiss Alpes) for frequencies between 0 and 2000 GHz () and typical atmospheric conditions using the forward model MOLIERE (version 5). For the DOME-C site, the transmission over a larger range of up to 10 THz () is calculated in order to demonstrate the quality of an Earth-bound site for mid-IR observations. All results are available on a dedicated webpage.  相似文献   

Land cover change and soil organic carbon stocks in the Republic of Ireland 1851–2000     

James M. Eaton  Nicola M. McGoff  Kenneth A. Byrne  Paul Leahy  Ger Kiely 《Climatic change》2008,91(3-4):317-334

Using both historic records and CORINE land cover maps, we assessed the impact of land cover change on the stock of soil organic carbon (SOC) in the Republic of Ireland from 1851 to 2000. We identified ten principal land cover classes: arable land, forest, grassland, heterogeneous agricultural areas/other, nonvegetated semi-natural areas, peatland, suburban, urban, water bodies, and wetland. For each land cover class, the SOC stock was estimated as the product of SOC density and land cover area. These were summed to calculate a national SOC budget for the Republic of Ireland. The Republic of Ireland’s 6.94 million hectares of land have undergone considerable change over the past 150 years. The most striking feature is the decrease in arable land from 1.44 million ha in 1851 to 0.55 million ha in 2000. Over the same time period, forested land increased by 0.53 million ha. As of 2000, agricultural lands including arable land (7.85%), grassland (54.33%), and the heterogeneous agricultural areas/other class (7.91%) account for 70.09% of Irish land cover. We estimate that the SOC stock in the Republic of Ireland, to 1 m depth, has increased from 1,391 Tg in 1851 to 1,469 Tg in 2000 despite soil loss due to urbanization. This increase is largely due to the increase of forested land with its higher SOC stocks when compared to agricultural lands. Peatlands contain a disproportionate quantity of the SOC stock. Although peatlands only occupy 17.36% of the land area, as of 2000, they represented 36% of the SOC stock (to 1 m depth).  相似文献   

Stability at high pressure, elastic behavior and pressure-induced structural evolution of “Al5BO9”, a mullite-type ceramic material     

G. Diego Gatta  Nicola Rotiroti  Martin Fisch  Thomas Armbruster 《Physics and Chemistry of Minerals》2010,37(4):227-236

Elastic behavior and pressure-induced structural evolution of synthetic boron-mullite “Al₅BO₉” (a = 5.678(2) Å, b = 15.015(4) Å and c = 7.700(3) Å, space group Cmc2₁, Z = 4) were investigated up to 7.4 GPa by in situ single-crystal X-ray diffraction with a diamond anvil cell under hydrostatic conditions. No phase transition or anomalous compressional behavior occurred within the investigated P range. Fitting the P–V data with a truncated second-order (in energy) Birch-Murnaghan Equation-of-State (BM-EoS), using the data weighted by the uncertainties in P and V, we obtained: V ₀ = 656.4(3) Å³ and K _T0 = 165(7) GPa (β _V0 = 0.0061(3) GPa^?1). The evolution of the Eulerian finite strain versus normalized stress (f _E–F _E plot) leads to an almost horizontal trend, showing that a truncated second-order BM-EoS is appropriate to describe the elastic behavior of “Al₅BO₉” within the investigated P range. The weighted linear regression through the data points gives: F _E(0) = 159(11) GPa. Axial compressibility coefficients yielded: β _a  = 1.4(2) × 10^?3 GPa^?1, β _b  = 3.4(4) × 10^?3 GPa^?1, and β _c  = 1.7(3) × 10^?3 GPa^?1 (β _a :β _b :β _c  = 1:2.43:1.21). The highest compressibilities observed in this study within (100) can be ascribed to the presence of voids represented by five-membered rings of polyhedra: Al1–Al3–Al4–Al1–Al3, which allow accommodating the effect of pressure by polyhedral tilting. Polyhedral tilting around the voids also explains the higher compressibility along [010] than along [001]. The stiffer crystallographic direction observed here might be controlled by the infinite chains of edge-sharing octahedra running along [100], which act as “pillars”, making the structure less compressible along the a-axis than along the b- and c-axis. Along [100], compression can only be accommodated by deformation of the edge-sharing octahedra (and/or by compression of the Al–O bond lengths), as no polyhedral tilting can occur. In addition, a comparative elastic analysis among the mullite-type materials is carried out.  相似文献   

δB, Sr, Mg and B in a modern Porites coral: the relationship between calcification site pH and skeletal chemistry     

Nicola Allison  Adrian A. Finch 《Geochimica et cosmochimica acta》2010,74(6):1790-6360

Sr/Ca, B/Ca, Mg/Ca and δ¹¹B were determined at high spatial resolution across ∼1 year of a modern Hawaiian Porites lobata coral by secondary ion mass spectrometry (SIMS). We observe significant variations in B/Ca, Mg/Ca, Sr/Ca and δ¹¹B over short skeletal distances (nominally equivalent to periods of <20 days). This heterogeneity probably reflects variations in the composition of the extracellular calcifying fluid (ECF) from which the skeleton precipitates. Calcification site pH (total scale) was estimated from skeletal δ¹¹B and ranged from 8.3 to 8.8 (± ∼0.1) with a mean of ∼8.6. Sr/Ca and B/Ca heterogeneity is not simply correlated with calcification site pH, as might be expected if Ca-ATPase activity increases the pH and decreases the Sr/Ca and B(OH)₄⁻/CO₃²⁻ ratios of the ECF. We produced a simple model of the ECF composition and the skeleton deposited from it, over a range of calcium transport and carbonate scenarios, which can account for these observed geochemical variations. The relationship between the pH and Sr/Ca of the ECF is dependent on the concentration of DIC at the calcification site. At higher DIC concentrations the ECF has a high capacity to buffer the [H⁺] changes induced by Ca-ATPase pumping. Conversely, at low DIC concentrations, this buffering capacity is reduced and ECF pH changes more rapidly in response to Ca-ATPase pumping. The absence of a simple correlation between ECF pH and skeletal Sr/Ca implies that calcification occurred under a range of DIC concentrations, reflecting variations in the respiration and photosynthesis of the coral and symbiotic zooxanthellate in the overlying coral tissues. Our observations have important implications for the use of coral skeletons as indicators of palaeo-ocean pH.  相似文献